Dr Horrible aka Billy - An aspiring supervillain of the mad scientist variety with the catchphrase, "I've got a Ph.D in Horribleness." He desires to become a member of Bad Horse's Evil League of Evil and use his inventions to take over the world and enact social change for the betterment of humanity, whom he sees as ignorant to the problems of the world. His unintentionally humorous socio-political beliefs include the paradoxical idea of autocratic anarchism. As Billy, he struggles to make a romantic connection with Penny.
Penny - Dr. Horrible's love interest, whom he sees at the coin laundromat. She is idealistic and generous and volunteers at a homeless shelter. Her optimism clashes vividly with Billy's cynicism and misanthropy, and her benevolence with Captain Hammer's narcissism.

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